Of all search engines Google has one of the biggest indexes--though the exact size is unknown and the company is not currently issuing official estimates on this matter (Battle par. 3). Google covers indexed web pages as well as PDF, .ps, .doc, .xls, .txt, .ppt, .rtf, .asp, .wpd, and more. In addition, Google spider crawls non-indexed pages. The unindexed URLs can be identified in Google's results because they lack an extract, page size, and there is no cached copy of the page (Notess, Google Special Report par. 2).

For determining the order of search results, Google uses a system called PageRank™, which ranks web pages. Though the algorithm is proprietary and a business secret, publicly available information suggests that the basis of PageRank is analyzing a page link structure as an indicator of an individual page's value (Google Technology).
A factor presumably influencing a page ranking is the existing rankings of other pages linking to it. Pages with a higher rank will increase the rank of those pages they link to. In addition, Google also looks at the frequency with which a search term appears on a page, the order of the search terms, and assigns phrases a higher rank than it does to keywords.
Finally, according to the company, “Google goes far beyond the number of times a term appears on a page and examines all aspects of the page's content […] to determine if it's a good match for your query”. Though it is unclear what exactly all aspects of the page's content are and to which extent these are examined.
Default Boolean AND
Boolean OR is supported but it must be capitalized
Supports some nesting of Boolean operators
Phrase searching available using quotation marks
Search terms are not case sensitive
Automatic stemming; the use of stemming is not explicit on search results page; can be disabled by enclosing a word in quotation marks
Spell checking
Stop words: words omitted by Google appear at the top of the screen on the search results page. These words can be included by adding the "+" sign in front of it.
Minus symbol “-“ can be used to exclude a word or phrase
Display of results
Google shows document title, first few lines of text, page URL, size of page in kilobytes, link to cached version and “similar pages”. The “similar pages” feature in Google does not always display results that are thematically related. Because the similar pages are retrieved based on back linking, this feature will also display pages that are not thematically similar but that link to the same pages (SearchEngineWatch forums).
Figure 1 Display of search results in Google

Limits: Language, country, domain, date, some field searching. In addition, Google offers other search features, though they might not always work as advertised. For example, Google’s “link:” function is supposed to retrieve all pages linking to a particular site, but it only retrieves a portion of them.
Electronic Collection Development Policy>
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Relevance 4 |
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WelchWeb: Collection Development Policy for Electronic Resources
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Relevance 4 |
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Electronic Collections Development
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Relevance 5 |
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Collection Development Policy for Electronic Resources
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Relevance 4 |
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[Publib] Electronic Collection Development Policy
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Relevance 2 |
All five results in Google refer to the topic of digital collection development in libraries. Results number 1, 2, and 4 constitute examples of policy statements from American academic libraries, therefore their relevancy level is high. The third results was assigned the highest level of relevancy because this web page includes links to sample policies and other useful resources. Finally, result number 5 was the least relevant. This last result is simply a message sent to a listserv in which somebody is asking for information on the topic rather than offering it.
*Note: This search results were recorded on October 28th, 2006.